Introduction
A short history of the fuel cell
Grove's
"gas battery"
Fuel cells today
What exactly is a fuel cell?
Fuels for fuel cells
Many
sources of hydrogen
Fuel delivery packages
Hydrogen from fossil fuels
Hydrogen from water
Technology of the future
Global impact
Storing hydrogen
What is a fuel?
Water is a fuel
Who bears the real costs?
Skeletons in the closet
The hydrogen-water economy is coming!
Water based hydrogen production
Electrolyzers
Solar, wind and hydro power for electrolyzers
Photo-electrolysis
Photo-biological
Types of Fuel Cells
Operating
temperatures
Regenerative fuel cells
Systems & Components Overview
Photovoltaic fuel cell systems
Fuel
cells vs. batteries
Components of a PV fuel cell system
Wind or small hydro power
Add-ins for the system
Fuel cell configurations
Matching the PV panels to your needs
Powering the electrolyzer
Building an electrolyzer
Compressing the hydrogen
More resources
Building a PV panel for your electrolyzer
Figuring PV panel costs
Wiring the system
Support and use components
Housing the system
Control valve
PEM fuel cell components
MEA
basics
Purchasing MEAs and components
Surplus fuel cells
Building
the K18 Hard Graphite
Convection Single Slice Fuel Cell
K18 Fuel Cell - Tool list
K18 Fuel Cell - Materials list
About the materials
Buying
membrane electrode assemblies and components
Mounting the membrane electrode assembly
Rubber gaskets and spacers
Keep the components clean
Working with graphite
Obtaining graphite
End plates
Miscellaneous parts
Fuel cell jazz
Simple tools do the job
Wet
and dry bandsaw
Drill press
Setting up for fuel cells
Preparing the graphite
Buy
graphite pieces that fit your saw
Setting the water flow
Slabbing the graphite
Begin to cut
Fences
Ripping gauges
Plan the cuts carefully
Cut extra pieces
Err on the thicker side
Cut the plate to size
Sanding
Sanding surface and technique
Cleaning the bandsaw
Using the templates
Drilling the holes
Routing the vertical flow fields
Routing the serpentine flow fields
Routing the serpentine flow fields
Preparing the other parts
End
plates
Gas gaskets and spacers
Mylar surrounds for the MEA (membrane electrode
assembly)
Handling the MEA (membrane electrode assembly)
Assemble the MEA in the Mylar surround
Electrode plate materials
Cutting the electrodes
Gas entry ports
Fasteners
Assembling the K18 fuel cell
Testing fuel cells
Building
an electrolyzer
Buying an electrolyzer
Hook up the hydrogen
Precautions
Turn on the hydrogen
Meter readings
Test for continuity within the cell
Troubleshooting – no reading
Convection process
Electrolyzers
How electrolyzers work
Electrolytes
Applying electricity
Types of electrolyzers
The tank electrolyzer
Home-built electrolyzers
The electrolyte
Preparing the electrolyte
Safety precautions
Building the P38 electrolyzer
Tools
needed
Materials needed
Purpose of the P38
Use at your own risk
Electrode separators
A transparent electrolyzer
Nickel electrodes
Preparing the parts for assembly
Bottom cap
Height gauge
Maintaining the electrolyte level
Increasing amperage to the electrolyzer
Sealing the electrolyzer
Silicone cement vs. epoxy
Preparing screws and nuts
Epoxy the pipe to the bottom cap
Dry the seals and test
Aligning the top and bottom caps
Wiring it up
Filling the electrolyzer
Connecting to power
Scrubber
Vinegar
Building a scrubber
Inside tube length
Transparent scrubbers
Making an electrolyte
Tools
needed
The filter bucket
The drip bucket
Add ashes and water
Wait 3 days to a week
Collect the KOH solution
Building
the L78 Soft Graphite
Convection Single Slice Fuel Cell
Tool and materials list
Tools
Materials needed
Really simple tools do the job
Stick
technology
Make it on your kitchen table
Print out the templates
Endplate/current collectors
Mark the end plates
Cut and drill the end plates
Soft graphite
Practice with the material
Cutting the soft graphite
Working with soft graphite
Drilling holes in soft graphite
Mark the flow fields
Making the flow field grooves
Soft graphite is forgiving
Easy construction and high performance
Aligning the holes
The hose connectors
Prepare the fasteners
Prepare the MEA
Assemble the fuel cell
Designing Fuel Cells
Ideas for designing fuel cells
Fuel
cell geometry
Buckyballs
Ceramics in fuel cells
Wooden fuel cells
Carbonizing other materials
Other natural materials for inspiration
"Biomimicry" for fuel cells
Collect supplier catalogs
Learn from the materials
Thinner and lighter designs
Use easy to obtain materials and tools
End plate materials
Plastics in fuel cells
General materials considerations
Convection vs. oxygen-hydrogen
Planning for maintenance
Banded fuel cells
Gas port plate
Stack design considerations - hardware
Longevity
Operating environment
In summary
Building stacks
Bipolar
plates
Plate thickness and groove depth
Gas feed in the gasket
Stack templates
Convection stack configuration
Oxygen-hydrogen stack configuration
Plan for easy disassembly
Larger stacks need gas pressure
Gas flow regulator
Additions to optimize performance
Gasket thickness affects performance
Experimental
Methods for Making MEAs
(Membrane Electrode Assemblies)
About membrane electrode assemblies
MEA
components
Applying the catalyst to the substrate
1. Sputter diffusion
2. A Benjamin Franklin technique
Resources for the experimenter
3. Electrochemical deposition
4. Electroless deposition
5. Mechanical Deposition
Powdering platinum
Carbon nano-tubes
Carbon and platinum mixtures
6. Electrostatic dispersion
7. Simple mixing
8. Photochemical
Platinum black
Application techniques
Brewster's reaction
Other methods to get platinum black
MEA - Tool list
MEA - Materials list
Loading the catalyst - an experimental method
Making
percent solutions
MEA components
The substrate and catalyst
Construction overview
Planning to load the catalyst
Carbon cloth substrate
Cutting the cloth
Weighing the chemicals
Safety precautions
The work area
Safelight conditions
Timing and storage
Making the solution
Handling AFO
Procedure summary
Preparing the platinum solution
Water bath
Making the platinum solution
Use a brush with no metal
Coating the carbon cloth
Make a test paper
Dry the fabric pieces
Expose to UV
Washing out the ferrous salts
Other washing methods
Preparing the proton exchange membrane (PEM)
Membrane
thickness
Handling the membrane
Membrane preparation
Bathing the membrane
Keep a steady temperature
Safety precautions
Keeping the membrane immersed
The first two baths
Fishing for the invisible membrane
The third bath
Last three baths
Pressing plates
Coat plate with powdered graphite
Lay out the MEA layers
Add the top plate carefully
Clamp the sandwich
Cook the sandwich
Increase the pressure
Further experiments
Lower
the loading
Increase the loading
Matching gaskets to MEAs
What to expect from your MEA
Testing fuel cells
Basic test equipment
Resources
Links
Books
Supplier contact information
MSDS
Templates
How to use the templates
K18
single slice convection
P38 Electrolyzer
L78 single slice convection
K18 single slice oxygen hydrogen
L78 single slice oxygen hydrogen
K18 convection stack
K18 oxygen hydrogen stack
Surround gasket with feed tunnels